Niobium monoxide

Niobium monoxide is the inorganic compound with the formulaNbO. It is a grey solid with metallic conductivity.^[1]

NbO adopts an unusual cubic structure, similar to the rock salt structure but with some missing atoms compared to it, so that both niobium and oxygen atoms have square planar coordination geometries. The niobium centers are arranged in octahedra, and there is a structural similarity to the octahedral niobium clusters in lower halides of niobium. In NbO the Nb–Nb bond length is 298 pm which compares to 285 pm in the metal.^[2] One study of the bonding concludes that strong and nearly covalent bonds exist between the metal centers.^[5]

It is a superconductor with a transition temperature of 1.38 K.^[6] It is used in capacitors where a layer of Nb₂O₅ is formed around NbO grains as the dielectric.^[7][8][9]

NbO can be prepared by reduction of Nb₂O₅ by hydrogen. More typically, it is prepared by comproportionation:^[10]

Nb₂O₅ + 3 Nb → 5 NbO

• Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). Boca Raton, Florida: CRC Press. ISBN 9781498754293.